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| KNOW HOW： |
Production of secondary butyl alcohol via n-butene hydration |
| Usage： |
Technologies For Refinery Gas Utilization |
| Keyword： |
secondary butyl alcohol, n-butene hydration |
| Remarks： |
R & D Background:
Methylethyl ketone (MEK) is an excellent organic solvent, which is widely used in synthetic resin (cellulose nitrate, vinyl resin, propenyl resin etc), rubber adhesive, magnetic type, printing ink, lube dewaxing, and etc. Secondary butyl alcohol is the only material for MEK production. Moreover, in China, the production of secondary butyl alcohol cannot meet the demand of market. The annual import these years is over 100,000 tons.
FRIPP started the process study for producing MEK through n-butene direct hydration and subsequent dehydrogenation. On the basis of the process study, DNM-type catalyst for butane hydration and FDH-type catalyst for secondary vinyl alcohol dehydrogenation have also been developed.
Features
*The hydration process uses low LHSV and high water/n-butene ratio, which results in low n-butene recycling and low energy cost.
*High yield for secondary vinyl alcohol and low organics content in discharging water, which decrease pollution to the environment.
*Dehydrogenation catalyst has long run length.
Summary:
Isopropanol (and its derivative acetone) and MEK are high value chemical materials that demand large quantities of import. As a high-octane gasoline blending component, secondary vinyl alcohol has great market potential. Therefore, hydration, being an efficient way for C3 and C4 utilization, will attract more and more attention in petrochemical industry. Besides the above-mentioned technologies, FRIPP has also developed the technology for synthesizing diphenylamine and subsequent products from aniline, technology for producing 1, 4-butanediol through etherification and hydrogenation of maleic anhydride. All these technologies, we are sure , will bring considerable economic benefits to enterprises.
Unit:
China Petroleum & Chemical Corporation Fushun Research Institute of Petroleum & Petrochemicals
Address: East 31, Dandong Rd, Wanghua, Fushun, Liaoning 113001,P. R. China
E-mail:intdep@fripp.com.cn
Tel:0086 413 6389215
Fax:0086 413 6429913
Website:www.fripp.com.cn |
| Original file： |
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Promulgator Info |
| Full name: |
administrator |
| Country: |
CN |
| City: |
Dalian |
| Company Name: |
teloon Soft Strategy Co.,LTD |
| Homepage: |
http://www.hqsq.net |
| E-mail: |
reply |
| Phone: |
86-411-82811662 |
| Fax: |
86-411-82819667 |
| Company Address: |
26 Renmin Road ,Dalian China |
| Zip/Postal Code: |
116001 |
| Introduction: |
As a professional E-information service platform with authoritative news and reports in chemical industry of chinese export and import market.Hichem has been received universally and praised highly since its established in 2001.In 2003,by joint effort of teloon chemicals and teloon soft strategy company(TSSC),Hichem team endeavored to recomposition the site ascribed to market requirement as well as offering our better service.Hichem focused on business to biusiness of new chemicals,fine chemicals,high chemicals and special chemicals.So naturally it is the very one-stop website for chemical information.Our sellers worldwide and build global on-line trade in the chemical industry. |
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