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  Site: Index >> Technology >> Chemical Thesis >> Thesis Detail

Thesis Name: Mesoporous silicates prepared using preorganized templates in supercritical fluids.
Usage: Mesoporous silicates
Keyword: Mesoporous silicates
Remarks: Well-ordered mesoporous silicate films were prepared by infusion and selective condensation of silicon alkoxides within microphase-separated block copolymer templates dilated with supercritical carbon dioxide. Confinement of metal oxide deposition to specific subdomains of the preorganized template yields high-fidelity, three-dimensional replication of the copolymer morphology, enabling the preparation of structures with multiscale order in a process that closely resembles biomineralization. Ordered mesoporous silicate films were synthesized with dielectric constants as low as 1.8 and excellent mechanical properties. The films survive the chemical-mechanical polishing step required for device manufacturing.
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