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| Thesis Name： |
Reactions of electron-deficient alkynes and allenes under phosphine catalysis |
| Usage： |
chemistry |
| Keyword： |
GAMMA-ADDITION REACTION; BAYLIS-HILLMAN REACTION; DIMETHYL ACETYLENEDICARBOXYLATE; WITHDRAWING GROUP |
| Remarks： |
The development of some new synthetic reactions derived from nucleophilic addition of phosphines to electron-deficient carbon-carbon triple bonds is described. These reactions show that the phosphine plays the role of a nucleophile as well as an excellent leaving group. The central problem is to generate a 1,3-dipole from atkynoates or allenoates; (2,3-butadienoates) by interaction with various phosphines. This study illuminates the unusual phenomena and shows how this understanding allows control of the reaction.
URL:http://pubs.acs.org/cgi-bin/article.cgi/achre4/2001/34/i07/pdf/ar000253x.pdf |
| Original file： |
No File
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Promulgator Detail |
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| Country: |
CN |
| City: |
Dalian |
| Company Name: |
teloon Soft Strategy Co.,LTD |
| Homepage: |
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